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Information card for entry 7113816
Preview
| Coordinates | 7113816.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C176 H136 Ag6 F12 N8 O12 P10 Re4 |
|---|---|
| Calculated formula | C176 H136 Ag6 F12 N8 O12 P10 Re4 |
| SMILES | [Ag]123[P](c4ccccc4)(c4ccccc4)C[P](c4ccccc4)(c4ccccc4)[Ag]4[C]1(=C=C=C=[Re]1(C#[O])(C#[O])(C#[O])[n]5ccc(cc5c5[n]1ccc(c5)C)C)[Ag]1[C]5(=C=C=C=[Re]6(C#[O])(C#[O])(C#[O])[n]7ccc(cc7c7[n]6ccc(c7)C)C)[Ag]([C]2(=C=C=C=[Re]2(C#[O])(C#[O])(C#[O])[n]6ccc(cc6c6[n]2ccc(c6)C)C)[Ag]2[P](c6ccccc6)(c6ccccc6)C[P](c6ccccc6)(c6ccccc6)[Ag]5([P](c5ccccc5)(c5ccccc5)C[P]1(c1ccccc1)c1ccccc1)[C]42=C=C=C=[Re]1(C#[O])(C#[O])(C#[O])[n]2ccc(cc2c2[n]1ccc(c2)C)C)[P](c1ccccc1)(c1ccccc1)C[P]3(c1ccccc1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-] |
| Title of publication | Synthesis and luminescence behaviour of novel heterodecanuclear silver(I)–rhenium(I) alkynyl complexes. X-Ray crystal structures of [Ag6(μ-dppm)4{μ3-C≡CC≡C–Re(Me2bpy)(CO)3}4](PF6)2 and [Ag6(μ-dppm)4{μ3-C≡CC≡C–Re(Br2phen)(CO)3}4](PF6)2 |
| Authors of publication | Yam, Vivian Wing-Wah; Lo, Wing-Yin; Zhu, Nianyong |
| Journal of publication | Chemical Communications (Cambridge, United Kingdom) |
| Year of publication | 2003 |
| Journal issue | 19 |
| Pages of publication | 2446 - 2447 |
| a | 20.082 ± 0.004 Å |
| b | 29.961 ± 0.006 Å |
| c | 35.827 ± 0.007 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 21556 ± 7 Å3 |
| Cell temperature | 293 ± 2 K |
| Ambient diffraction temperature | 293 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 19 |
| Hermann-Mauguin space group symbol | P 21 21 21 |
| Hall space group symbol | P 2ac 2ab |
| Residual factor for all reflections | 0.1131 |
| Residual factor for significantly intense reflections | 0.0683 |
| Weighted residual factors for significantly intense reflections | 0.1819 |
| Weighted residual factors for all reflections included in the refinement | 0.2123 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.996 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 297215 (current) | 2025-01-08 | Updated bibliography in entries 7113816-7113817. |
7113816.cif |
| 180252 | 2016-03-26 | cif/7/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/11/38. |
7113816.cif |
| 115289 | 2014-06-02 | cif/ Adding structures of 7113816, 7113817 via cif-deposit CGI script. |
7113816.cif |
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Users of the data should acknowledge the original authors of the
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