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Information card for entry 7113877
Preview
| Coordinates | 7113877.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C40 H96 Cl2 In3 Rh Si9 |
|---|---|
| Calculated formula | C40 H96 Cl2 In3 Rh Si9 |
| SMILES | [Cl]1[In]2([Cl][In]([Rh]34562([c]2([c]3([c]6([c]5([c]42C)C)C)C)C)[In]1C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C |
| Title of publication | Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal‒group 13 metal bond formation |
| Authors of publication | Steinke, Tobias; Gemel, Christian; Cokoja, Mirza; Winter, Manuela; Fischer, Roland A. |
| Journal of publication | Chemical Communications (Cambridge, United Kingdom) |
| Year of publication | 2003 |
| Journal issue | 9 |
| Pages of publication | 1066 - 1067 |
| a | 14.509 ± 0.003 Å |
| b | 18.83 ± 0.004 Å |
| c | 22.633 ± 0.004 Å |
| α | 90° |
| β | 92.882 ± 0.004° |
| γ | 90° |
| Cell volume | 6176 ± 2 Å3 |
| Cell temperature | 213 ± 2 K |
| Ambient diffraction temperature | 213 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0617 |
| Residual factor for significantly intense reflections | 0.0417 |
| Weighted residual factors for significantly intense reflections | 0.0943 |
| Weighted residual factors for all reflections included in the refinement | 0.1039 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.023 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Duplicate of | 7104100 |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 210396 (current) | 2018-09-04 | cif/7/ Updating bibliography in entries 7104100-7104101, 7113877-7113878. Marking entries 7113877-7113878 as duplicates of entries 7104100-7104101. |
7113877.cif |
| 180252 | 2016-03-26 | cif/7/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/11/38. |
7113877.cif |
| 115325 | 2014-06-03 | cif/ Adding structures of 7113877, 7113878 via cif-deposit CGI script. |
7113877.cif |
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