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Information card for entry 7113878
Preview
| Coordinates | 7113878.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C40 H60 Cl2 In3 Rh |
|---|---|
| Calculated formula | C40 H60 Cl2 In3 Rh |
| SMILES | [Rh]12345([c]6(C)[c]3([c]2([c]4([c]56C)C)C)C)([In]([Cl][In]23451[c]1([c]5(C)[c]3([c]4(C)[c]21C)C)C)(Cl)C1(C(=C(C(=C1C)C)C)C)C)[In]1234[c]5([c]1(C)[c]2([c]3([c]45C)C)C)C |
| Title of publication | Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal‒group 13 metal bond formation |
| Authors of publication | Steinke, Tobias; Gemel, Christian; Cokoja, Mirza; Winter, Manuela; Fischer, Roland A. |
| Journal of publication | Chemical Communications (Cambridge, United Kingdom) |
| Year of publication | 2003 |
| Journal issue | 9 |
| Pages of publication | 1066 - 1067 |
| a | 10.732 ± 0.019 Å |
| b | 21.72 ± 0.04 Å |
| c | 35.49 ± 0.05 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 8273 ± 2 Å3 |
| Cell temperature | 213 ± 2 K |
| Ambient diffraction temperature | 213 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 61 |
| Hermann-Mauguin space group symbol | P b c a |
| Hall space group symbol | -P 2ac 2ab |
| Residual factor for all reflections | 0.0906 |
| Residual factor for significantly intense reflections | 0.0558 |
| Weighted residual factors for significantly intense reflections | 0.1241 |
| Weighted residual factors for all reflections included in the refinement | 0.1392 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.037 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Duplicate of | 7104101 |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 210396 (current) | 2018-09-04 | cif/7/ Updating bibliography in entries 7104100-7104101, 7113877-7113878. Marking entries 7113877-7113878 as duplicates of entries 7104100-7104101. |
7113878.cif |
| 180252 | 2016-03-26 | cif/7/11/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/11/38. |
7113878.cif |
| 115325 | 2014-06-03 | cif/ Adding structures of 7113877, 7113878 via cif-deposit CGI script. |
7113878.cif |
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Users of the data should acknowledge the original authors of the
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