Crystallography Open Database

Information card for entry 7234378

Preview

Coordinates	7234378.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C176 H312 Mn2 Mo12 N34 O61
Calculated formula	C176 H312 Mn2 Mo12 N34 O61
Title of publication	Bimetallic MnIII-FeII hybrid complexes formed by a functionalized MnIII Anderson polyoxometalate coordinated to FeII: observation of a field-induced slow relaxation of magnetization in the MnIII centres and a photoinduced spin-crossover in the FeII centres
Authors of publication	Alexandre Abherve; Mario Palacios-Corella; Juan Modesto Clemente-Juan; Raphael Marx; Petr Neugebauer; Joris van Slageren; Miguel Clemente-Leon; Eugenio Coronado
Journal of publication	Journal of Materials Chemistry C
Year of publication	2015
Journal volume	3
Pages of publication	7936 - 7945
a	18.6735 ± 0.0002 Å
b	21.7084 ± 0.0002 Å
c	28.6619 ± 0.0004 Å
α	90°
β	108.87 ± 0.001°
γ	90°
Cell volume	10994.3 ± 0.2 Å³
Cell temperature	119.95 ± 0.1 K
Ambient diffraction temperature	120 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.073
Residual factor for significantly intense reflections	0.0436
Weighted residual factors for significantly intense reflections	0.0925
Weighted residual factors for all reflections included in the refinement	0.1083
Goodness-of-fit parameter for all reflections included in the refinement	1.034
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
219096 (current)	2019-10-04	cif/ Adding structures of 7234378, 7234379 via cif-deposit CGI script.	7234378.cif