Crystallography Open Database

Information card for entry 7234379

Preview

Coordinates	7234379.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C38 H44 Fe2 Mn Mo6 N14 O32
Calculated formula	C38 H44 Fe2 Mn Mo6 N14 O32
Title of publication	Bimetallic MnIII-FeII hybrid complexes formed by a functionalized MnIII Anderson polyoxometalate coordinated to FeII: observation of a field-induced slow relaxation of magnetization in the MnIII centres and a photoinduced spin-crossover in the FeII centres
Authors of publication	Alexandre Abherve; Mario Palacios-Corella; Juan Modesto Clemente-Juan; Raphael Marx; Petr Neugebauer; Joris van Slageren; Miguel Clemente-Leon; Eugenio Coronado
Journal of publication	Journal of Materials Chemistry C
Year of publication	2015
Journal volume	3
Pages of publication	7936 - 7945
a	24.221 ± 0.005 Å
b	16.6 ± 0.003 Å
c	16.512 ± 0.003 Å
α	90°
β	97.76 ± 0.02°
γ	90°
Cell volume	6578 ± 2 Å³
Cell temperature	180 ± 2 K
Ambient diffraction temperature	180 ± 2 K
Number of distinct elements	7
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.1679
Residual factor for significantly intense reflections	0.0953
Weighted residual factors for significantly intense reflections	0.2401
Weighted residual factors for all reflections included in the refinement	0.3045
Goodness-of-fit parameter for all reflections included in the refinement	0.991
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
219096 (current)	2019-10-04	cif/ Adding structures of 7234378, 7234379 via cif-deposit CGI script.	7234379.cif