Crystallography Open Database

Information card for entry 7246158

Preview

Coordinates	7246158.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C52 H37 O9 Os3 P2 Sb
Calculated formula	C52 H37 O9 Os3 P2 Sb
SMILES	[Os]12([Os]([Os]1([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O]
Title of publication	Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
Authors of publication	Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
Journal of publication	RSC Advances
Year of publication	2023
Journal volume	13
Journal issue	5
Pages of publication	2841 - 2851
a	42.6814 ± 0.0013 Å
b	11.4302 ± 0.0003 Å
c	19.993 ± 0.0006 Å
α	90°
β	90.434 ± 0.002°
γ	90°
Cell volume	9753.4 ± 0.5 Å³
Cell temperature	210 ± 1 K
Ambient diffraction temperature	210 ± 1 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0296
Residual factor for significantly intense reflections	0.0215
Weighted residual factors for significantly intense reflections	0.0448
Weighted residual factors for all reflections included in the refinement	0.0479
Goodness-of-fit parameter for all reflections included in the refinement	1.029
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
280427 (current)	2023-01-19	cif/ Adding structures of 7246158, 7246159, 7246160, 7246161 via cif-deposit CGI script.	7246158.cif