Crystallography Open Database

Information card for entry 7246159

Preview

Coordinates	7246159.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C51 H39 Cl2 O7 Os3 P2 Sb
Calculated formula	C51 H39 Cl2 O7 Os3 P2 Sb
SMILES	[Os]1234([Os]5([Os]1([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])([c]13c([P]5(C[P]2(c2ccccc2)c2ccccc2)c2ccccc2)cccc1)[H]4)(C#[O])(C#[O])C#[O])(C#[O])C#[O].C(Cl)Cl
Title of publication	Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
Authors of publication	Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
Journal of publication	RSC Advances
Year of publication	2023
Journal volume	13
Journal issue	5
Pages of publication	2841 - 2851
a	19.6929 ± 0.001 Å
b	13.9599 ± 0.0007 Å
c	20.1424 ± 0.001 Å
α	90°
β	113.639 ± 0.001°
γ	90°
Cell volume	5072.7 ± 0.4 Å³
Cell temperature	210 ± 1 K
Ambient diffraction temperature	210 ± 1 K
Number of distinct elements	7
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0522
Residual factor for significantly intense reflections	0.029
Weighted residual factors for significantly intense reflections	0.0498
Weighted residual factors for all reflections included in the refinement	0.0559
Goodness-of-fit parameter for all reflections included in the refinement	1.025
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
280427 (current)	2023-01-19	cif/ Adding structures of 7246158, 7246159, 7246160, 7246161 via cif-deposit CGI script.	7246159.cif