Crystallography Open Database

Information card for entry 7246160

Preview

Coordinates	7246160.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C69 H52 O8 Os3 P2 Sb2
Calculated formula	C69 H52 O8 Os3 P2 Sb2
SMILES	[Os]12([Os]([Os]([Sb]1(c1ccccc1)c1ccccc1)([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])c1ccccc1
Title of publication	Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
Authors of publication	Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
Journal of publication	RSC Advances
Year of publication	2023
Journal volume	13
Journal issue	5
Pages of publication	2841 - 2851
a	11.9842 ± 0.0005 Å
b	12.2615 ± 0.0004 Å
c	22.7266 ± 0.0009 Å
α	101.908 ± 0.002°
β	98.475 ± 0.002°
γ	94.176 ± 0.002°
Cell volume	3213.6 ± 0.2 Å³
Cell temperature	193 ± 1 K
Ambient diffraction temperature	193 ± 1 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0482
Residual factor for significantly intense reflections	0.0298
Weighted residual factors for significantly intense reflections	0.0589
Weighted residual factors for all reflections included in the refinement	0.0642
Goodness-of-fit parameter for all reflections included in the refinement	1.026
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
280427 (current)	2023-01-19	cif/ Adding structures of 7246158, 7246159, 7246160, 7246161 via cif-deposit CGI script.	7246160.cif