Crystallography Open Database

Information card for entry 7246161

Preview

Coordinates	7246161.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C68 H52 O7 Os3 P2 Sb2
Calculated formula	C68 H52 O7 Os3 P2 Sb2
SMILES	[Os]1234([Os]([Os]([Sb]1(c1ccccc1)c1ccccc1)([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])(c1c3cccc1)[H]4)(C#[O])C#[O]
Title of publication	Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
Authors of publication	Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
Journal of publication	RSC Advances
Year of publication	2023
Journal volume	13
Journal issue	5
Pages of publication	2841 - 2851
a	15.1736 ± 0.0004 Å
b	20.3459 ± 0.0006 Å
c	21.9689 ± 0.0006 Å
α	90°
β	90°
γ	90°
Cell volume	6782.3 ± 0.3 Å³
Cell temperature	210 ± 1 K
Ambient diffraction temperature	210 ± 1 K
Number of distinct elements	6
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0286
Residual factor for significantly intense reflections	0.0265
Weighted residual factors for significantly intense reflections	0.0596
Weighted residual factors for all reflections included in the refinement	0.0603
Goodness-of-fit parameter for all reflections included in the refinement	1.116
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
280427 (current)	2023-01-19	cif/ Adding structures of 7246158, 7246159, 7246160, 7246161 via cif-deposit CGI script.	7246161.cif