Crystallography Open Database

Information card for entry 7700250

Preview

Coordinates	7700250.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C65 H135 Li4 N7 Si4
Calculated formula	C65 H135 Li4 N7 Si4
Title of publication	The smaller, the better? How the aggregate size affects the reactivity of (trimethylsilyl)methyllithium.
Authors of publication	Knauer, Lena; Wattenberg, Jonathan; Kroesen, Ulrike; Strohmann, Carsten
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2019
Journal volume	48
Journal issue	30
Pages of publication	11285 - 11291
a	21.75 ± 0.003 Å
b	12.1145 ± 0.0015 Å
c	31.14 ± 0.005 Å
α	90°
β	105.61 ± 0.004°
γ	90°
Cell volume	7902.5 ± 1.9 Å³
Cell temperature	100 K
Ambient diffraction temperature	100 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.088
Residual factor for significantly intense reflections	0.0667
Weighted residual factors for significantly intense reflections	0.1861
Weighted residual factors for all reflections included in the refinement	0.1988
Goodness-of-fit parameter for all reflections included in the refinement	1.036
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
224341 (current)	2019-11-08	cif/ Updating files of 7700249, 7700250, 7700251 Original log message: Adding full bibliography for 7700249--7700251.cif.	7700250.cif
215906	2019-06-13	cif/ Adding structures of 7700249, 7700250, 7700251 via cif-deposit CGI script.	7700250.cif