Crystallography Open Database

Information card for entry 7709361

Preview

Coordinates	7709361.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C24 H98 Co4 N16 O57 Si4 V16
Calculated formula	C24 H72 Co4 N16 O47 Si4 V16
Title of publication	Three Si-substituted polyoxovanadates as efficient catalysts for Knoevenagel condensation and selective oxidation of styrene to benzaldehyde.
Authors of publication	Shi, Yu; Zhou, Tong; Di, Jia-Qi; Wang, Wenhui; Ma, Li; Zhang, Heng; Gao, Yuanzhe
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2022
Journal volume	51
Journal issue	8
Pages of publication	3304 - 3313
a	12.8549 ± 0.0013 Å
b	13.2678 ± 0.0013 Å
c	14.8024 ± 0.0014 Å
α	69.796 ± 0.002°
β	64.329 ± 0.002°
γ	81.152 ± 0.002°
Cell volume	2135.4 ± 0.4 Å³
Cell temperature	296 ± 2 K
Ambient diffraction temperature	296 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0704
Residual factor for significantly intense reflections	0.0463
Weighted residual factors for significantly intense reflections	0.1181
Weighted residual factors for all reflections included in the refinement	0.1313
Goodness-of-fit parameter for all reflections included in the refinement	1.069
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
273367 (current)	2022-03-05	cif/ Updating files of 7709360, 7709361, 7709362 Original log message: Adding full bibliography for 7709360--7709362.cif.	7709361.cif
272231	2022-01-26	cif/ Adding structures of 7709360, 7709361, 7709362 via cif-deposit CGI script.	7709361.cif