Crystallography Open Database

Information card for entry 7709360

Preview

Coordinates	7709360.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C20 H85 Cd4 N15 O56 Si6 V15
Calculated formula	C20 H63 Cd4 N15 O49 Si6 V15
Title of publication	Three Si-substituted polyoxovanadates as efficient catalysts for Knoevenagel condensation and selective oxidation of styrene to benzaldehyde.
Authors of publication	Shi, Yu; Zhou, Tong; Di, Jia-Qi; Wang, Wenhui; Ma, Li; Zhang, Heng; Gao, Yuanzhe
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2022
Journal volume	51
Journal issue	8
Pages of publication	3304 - 3313
a	20.788 ± 0.004 Å
b	19.333 ± 0.003 Å
c	44.011 ± 0.008 Å
α	90°
β	98.456 ± 0.003°
γ	90°
Cell volume	17495 ± 5 Å³
Cell temperature	296 ± 2 K
Ambient diffraction temperature	296 ± 2 K
Number of distinct elements	7
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.1329
Residual factor for significantly intense reflections	0.1091
Weighted residual factors for significantly intense reflections	0.253
Weighted residual factors for all reflections included in the refinement	0.2612
Goodness-of-fit parameter for all reflections included in the refinement	1.084
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
273367 (current)	2022-03-05	cif/ Updating files of 7709360, 7709361, 7709362 Original log message: Adding full bibliography for 7709360--7709362.cif.	7709360.cif
272231	2022-01-26	cif/ Adding structures of 7709360, 7709361, 7709362 via cif-deposit CGI script.	7709360.cif