Crystallography Open Database

Information card for entry 7710751

Preview

Coordinates	7710751.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Magnesium bis(2-thiopyridyl)methanide tetraphenyldiphosphine
Formula	C46 H38 Mg N4 P2 S4
Calculated formula	C46 H38 Mg N4 P2 S4
Title of publication	Synthesis, Characterisation and Reactivity of Group 2 Complexes with a Thiopyridyl Scorpionate Ligand
Authors of publication	Stevens, Matthew Philip; Spray, Emily; Vitorica-Yrzebal, Inigo; Singh, Kuldip; Timmermann, Vanessa M.; Sotorrios, Lia; Macgregor, Stuart Alan; Ortu, Fabrizio
Journal of publication	Dalton Transactions
Year of publication	2022
a	9.69497 ± 0.00018 Å
b	16.4661 ± 0.0003 Å
c	13.4773 ± 0.0002 Å
α	90°
β	108.214 ± 0.0019°
γ	90°
Cell volume	2043.69 ± 0.07 Å³
Cell temperature	100.02 ± 0.14 K
Ambient diffraction temperature	100.02 ± 0.14 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0359
Residual factor for significantly intense reflections	0.033
Weighted residual factors for significantly intense reflections	0.0837
Weighted residual factors for all reflections included in the refinement	0.0852
Goodness-of-fit parameter for all reflections included in the refinement	1.042
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
276839 (current)	2022-07-23	cif/ Adding structures of 7710749, 7710750, 7710751, 7710752, 7710753, 7710754, 7710755, 7710756 via cif-deposit CGI script.	7710751.cif