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Information card for entry 7711932
Preview
| Coordinates | 7711932.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | [{κP,κC-(i-Pr)2PO-(5-Cl-C6H3)}{κN-(PhCH2-)(PhCH=)N}Ni(Br)] |
|---|---|
| Formula | C26 H30 Br Cl N Ni O P |
| Calculated formula | C26 H30 Br Cl N Ni O P |
| SMILES | Br[Ni]1([P](Oc2c1ccc(Cl)c2)(C(C)C)C(C)C)[N](=Cc1ccccc1)Cc1ccccc1 |
| Title of publication | Reactivities of cyclonickellated complexes with hydroxylamines: formation of κ<sup>O</sup>-hydroxylamine and κ<sup>N</sup>-imine adducts and a κ<sup>O</sup>, κ<sup>N</sup>-aminoxide derivative. |
| Authors of publication | Sarker, Rajib K.; Mangin, Loïc P; Zargarian, Davit |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2023 |
| Journal volume | 52 |
| Journal issue | 2 |
| Pages of publication | 366 - 375 |
| a | 12.9011 ± 0.0005 Å |
| b | 15.7826 ± 0.0006 Å |
| c | 13.2566 ± 0.0005 Å |
| α | 90° |
| β | 107.169 ± 0.002° |
| γ | 90° |
| Cell volume | 2578.93 ± 0.17 Å3 |
| Cell temperature | 150 K |
| Ambient diffraction temperature | 150 K |
| Number of distinct elements | 8 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0518 |
| Residual factor for significantly intense reflections | 0.0374 |
| Weighted residual factors for significantly intense reflections | 0.0868 |
| Weighted residual factors for all reflections included in the refinement | 0.0935 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.05 |
| Diffraction radiation wavelength | 1.34139 Å |
| Diffraction radiation type | GaKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 283290 (current) | 2023-05-05 | cif/ Updating files of 7711929, 7711930, 7711931, 7711932, 7711933, 7711934, 7711935, 7711936, 7711937, 7711938, 7711939 Original log message: Adding full bibliography for 7711929--7711939.cif. |
7711932.cif |
| 279895 | 2022-12-15 | cif/ Adding structures of 7711929, 7711930, 7711931, 7711932, 7711933, 7711934, 7711935, 7711936, 7711937, 7711938, 7711939 via cif-deposit CGI script. |
7711932.cif |
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Users of the data should acknowledge the original authors of the
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