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Information card for entry 7714244
Preview
| Coordinates | 7714244.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C64 H90 Cl2 P2 Rh2 Si4 |
|---|---|
| Calculated formula | C64 H90 Cl2 P2 Rh2 Si4 |
| Title of publication | Unexpected alkyl isomerization at the silicon ligand of an unsaturated Rh complex: combined experiment and theory |
| Authors of publication | Abeynayake, Niroshani S.; Le, Nghia; Sanchez-Lecuona, Gabriela; Donnadieu, Bruno; Webster, Charles Edwin; Montiel-Palma, Virginia |
| Journal of publication | Dalton Transactions |
| Year of publication | 2023 |
| a | 19.691 ± 0.007 Å |
| b | 15.587 ± 0.007 Å |
| c | 20.196 ± 0.009 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 6199 ± 4 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 61 |
| Hermann-Mauguin space group symbol | P b c a |
| Hall space group symbol | -P 2ac 2ab |
| Residual factor for all reflections | 0.0426 |
| Residual factor for significantly intense reflections | 0.0316 |
| Weighted residual factors for significantly intense reflections | 0.081 |
| Weighted residual factors for all reflections included in the refinement | 0.0894 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.062 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 287022 (current) | 2023-10-19 | cif/ Adding structures of 7714244, 7714245 via cif-deposit CGI script. |
7714244.cif |
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