Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 7714245
Preview
| Coordinates | 7714245.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C32 H40 Cl O P Rh Si2 |
|---|---|
| Calculated formula | C32 H40 Cl O P Rh Si2 |
| Title of publication | Unexpected alkyl isomerization at the silicon ligand of an unsaturated Rh complex: combined experiment and theory |
| Authors of publication | Abeynayake, Niroshani S.; Le, Nghia; Sanchez-Lecuona, Gabriela; Donnadieu, Bruno; Webster, Charles Edwin; Montiel-Palma, Virginia |
| Journal of publication | Dalton Transactions |
| Year of publication | 2023 |
| a | 9.844 ± 0.005 Å |
| b | 11.815 ± 0.007 Å |
| c | 13.809 ± 0.008 Å |
| α | 102.799 ± 0.015° |
| β | 95 ± 0.02° |
| γ | 97.929 ± 0.016° |
| Cell volume | 1539.6 ± 1.5 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0519 |
| Residual factor for significantly intense reflections | 0.043 |
| Weighted residual factors for significantly intense reflections | 0.1067 |
| Weighted residual factors for all reflections included in the refinement | 0.1129 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.027 |
| Diffraction radiation wavelength | 1.54178 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 287022 (current) | 2023-10-19 | cif/ Adding structures of 7714244, 7714245 via cif-deposit CGI script. |
7714245.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.