Crystallography Open Database

Information card for entry 7714465

Preview

Coordinates	7714465.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	[K(18-c-6)][F-1]
Formula	C48 H46.78 F49.99 Ge2 K2 O20
Calculated formula	C48 H46.774 F49.997 Ge2 K2 O20
Title of publication	A neutral germanium-centred hard and soft lewis superacid and its unique reactivity towards hydrosilanes.
Authors of publication	Tschernuth, Florian S.; Kostenko, Arseni; Stigler, Sebastian; Gradenegger, Anna; Inoue, Shigeyoshi
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2023
Journal volume	53
Journal issue	1
Pages of publication	74 - 81
a	11.2001 ± 0.001 Å
b	15.7831 ± 0.0014 Å
c	22.3057 ± 0.0019 Å
α	107.062 ± 0.003°
β	102.834 ± 0.003°
γ	95.235 ± 0.003°
Cell volume	3623.2 ± 0.6 Å³
Cell temperature	100 K
Ambient diffraction temperature	100 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0451
Residual factor for significantly intense reflections	0.0348
Weighted residual factors for significantly intense reflections	0.0717
Weighted residual factors for all reflections included in the refinement	0.0765
Goodness-of-fit parameter for all reflections included in the refinement	1.087
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
289462 (current)	2024-02-04	cif/ Updating files of 7714462, 7714463, 7714464, 7714465, 7714466 Original log message: Adding full bibliography for 7714462--7714466.cif.	7714465.cif
287629	2023-11-16	cif/ Adding structures of 7714462, 7714463, 7714464, 7714465, 7714466 via cif-deposit CGI script.	7714465.cif