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Information card for entry 4088023
Preview
| Coordinates | 4088023.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C47 H58 B2 Cl4 F8 N5 P2 Rh |
|---|---|
| Calculated formula | C47 H58 B2 Cl4 F8 N5 P2 Rh |
| Title of publication | Synthesis, Isomerization, and Catalytic Transfer Hydrogenation Activity of Rhodium(III) Complexes Containing Both Chelating Dicarbenes and Diphosphine Ligands |
| Authors of publication | Farrell, Kevin; Müller-Bunz, Helge; Albrecht, Martin |
| Journal of publication | Organometallics |
| Year of publication | 2015 |
| Journal volume | 34 |
| Journal issue | 24 |
| Pages of publication | 5723 |
| a | 11.71475 ± 0.00007 Å |
| b | 23.193 ± 0.0002 Å |
| c | 19.8589 ± 0.0002 Å |
| α | 90° |
| β | 98.147 ± 0.0006° |
| γ | 90° |
| Cell volume | 5341.21 ± 0.08 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 9 |
| Hermann-Mauguin space group symbol | C 1 c 1 |
| Hall space group symbol | C -2yc |
| Residual factor for all reflections | 0.0223 |
| Residual factor for significantly intense reflections | 0.0218 |
| Weighted residual factors for significantly intense reflections | 0.0549 |
| Weighted residual factors for all reflections included in the refinement | 0.0552 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.037 |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 237222 (current) | 2019-11-24 | cif/ Adding structures of 4088023, 4088024, 4088025, 4088026 via cif-deposit CGI script. |
4088023.cif |
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Users of the data should acknowledge the original authors of the
structural data.